Issue 0, 1979

Synthesis and chemiluminescent reactions of some 3-alkoxycarbamoylbenzo[b]furan-2(3H)-ones

Abstract

The 3-alkoxycarbamoylbenzo[b]furan-2(3H)-ones (1)–(9) have been synthesised, and were found to chemiluminesce in dipolar aprotic solvents in the presence of oxygen and a base. The end products of the chemiluminescent reactions are benzoxazinediones (23), and a mechanism for their formation and the light emission is proposed. A side-reaction gives dehydrodimers (22) which are slowly converted into the benzoxazinediones with weak chemiluminescence

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1979, 1634-1639

Synthesis and chemiluminescent reactions of some 3-alkoxycarbamoylbenzo[b]furan-2(3H)-ones

G. J. Lofthouse, H. Suschitzky, B. J. Wakefield, R. A. Whittaker and B. Tuck, J. Chem. Soc., Perkin Trans. 1, 1979, 1634 DOI: 10.1039/P19790001634

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