Issue 0, 1979
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Migration of the diphenylphosphinoyl group in competition with the phenylthio-, methylthio-, or methoxy-groups from the same migration origin

Chris Earnshaw,   J. Ian Grayson  and  Stuart Warren  

Abstract

When both functional groups are present at the same migration origin. Ph2PO migrates in preference to MeO. Either Ph2PO or RS may migrate depending on the substituents at the migration terminus. Fragmentation reactions compete with rearrangement in both cases. 13C N.m.r. spectra of reactants and products are reported.

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Article information

DOI
https://doi.org/10.1039/P19790001506
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1979, 1506-1514

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Migration of the diphenylphosphinoyl group in competition with the phenylthio-, methylthio-, or methoxy-groups from the same migration origin

C. Earnshaw, J. I. Grayson and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1979, 1506 DOI: 10.1039/P19790001506

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