The quenching of I(52P½) by HCl has been studied over the temperature range 200–400 K, using time-resolved atomic absorption spectrophotometry (λ= 206 nm). The quenching efficiency was found to increase smoothly over this range supporting a previously proposed curve crossing mechanism. The results also provide information on non-adiabatic coupling in the exit channels for reaction of H with ICl and Cl with HI.
C. Fotakis and R. J. Donovan, J. Chem. Soc., Faraday Trans. 2, 1979, 75, 1553 DOI: 10.1039/F29797501553
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