Mixed ligand complexes in solution of manganous ion. Nuclear relaxation rate analysis

Abstract

The use of Mn^II as a paramagnetic relaxation probe in n.m.r. analysis of mixed-ligand solutions has been examined. Evidence for ternary complex formation has been made possible by means of various experimental devices. The analysis of nuclear relaxation rates of both ligand and solvent molecules has been performed, suggesting an emphasis on relaxation reagents as far as biological inferences are concerned.