The rate of the CoIII+ FeII reaction in 3 mol dm–3 HClO4 is obtained by amperometry and confirms (corrected) results from stopped-flow experiments. Three current questions about the state and reactivity of CoIII are discussed and partly resolved; in particular E° for CoIII/CoII is confirmed as being 1.8–1.9 V.
D. R. Rosseinsky and G. A. Jauregui, J. Chem. Soc., Faraday Trans. 1, 1979, 75, 473 DOI: 10.1039/F19797500473
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