The reactions of CO with trans-[M(PPh3)2(CS)(N3)](M = Ir or Rh) in benzene or chloroform solution result in the formation of trans-[M(PPh3)2(CO)(NCS)] rather than trans-[M(PPh3)2(CS)(NCO)]. Paths for the reactions including atom transfer in a five-co-ordinate intermediate and nucleophilic attack of co-ordinated CS by azide ion are discussed.
M. Kubota and T. G. Chappell, J. Chem. Soc., Dalton Trans., 1979, 406 DOI: 10.1039/DT9790000406
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