Issue 21, 1979

Kinetic deuterium isotope effect in the protonation of cryptand [2,1,1], (1,10-diaza-4,7,13,18-tetraoxabicyclo[8.5.5]eicosane) by water

Abstract

The protonation of cryptand [2,1,1] by water displays large kinetic deuterium effects suggesting that the process involves direct proton transfer through the cryptand molecular framework.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 965b-966

Kinetic deuterium isotope effect in the protonation of cryptand [2,1,1], (1,10-diaza-4,7,13,18-tetraoxabicyclo[8.5.5]eicosane) by water

A. M. Kjær, P. E. Sørensen and J. Ulstrup, J. Chem. Soc., Chem. Commun., 1979, 965b DOI: 10.1039/C3979000965B

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