The bicyclic αβ-unsaturated ketone (2), conveniently prepared by thermal rearrangement of (1), is converted, via an 11-step sequence, into the tricyclic ketone (15), thus formally completing a new total synthesis of (±)-zizaene (3).
E. Piers and J. Banville, J. Chem. Soc., Chem. Commun., 1979, 1138 DOI: 10.1039/C39790001138
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