Issue 24, 1979

Nucleophilic addition to (methyl α-chloroacrylate)tetracarbonyliron. Activation of a vinyl halide

Abstract

Treatment of the title complex with stabilized anions under aprotic conditions followed by acid affords products corresponding to vicinal incorporation of two equivalents of nucleophile by a process which probably involves an ironcarbene complex.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 1129-1130

Nucleophilic addition to (methyl α-chloroacrylate)tetracarbonyliron. Activation of a vinyl halide

M. R. Baar and B. W. Roberts, J. Chem. Soc., Chem. Commun., 1979, 1129 DOI: 10.1039/C39790001129

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