The new zerovalent metal phosphite complex, W[P(OMe)3]6, has been synthesized and shown to be photochemically very reactive as illustrated in the synthesis of a series of new seven- and eight-co-ordinate tungsten hydrides.
H. W. Choi, R. M. Gavin and E. L. Muetterties, J. Chem. Soc., Chem. Commun., 1979, 1085 DOI: 10.1039/C39790001085
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