The absolute configuration of isositsirikine (2a), an alkaloid of C. roseus, has been determined by enzymatic conversion from geissoschizine (1) and comparison with authentic samples of known chirality.
T. Hirata, S. Lee and A. I. Scott, J. Chem. Soc., Chem. Commun., 1979, 1081 DOI: 10.1039/C39790001081
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