SCHEDULED MAINTENANCE
Enhanced absorption CIDNP is observed for the chloroform proton and for the terminal olefinic protons of NN-diethylvinylamine during photolysis of the triethylamine–carbon tetrachloride charge transfer complex in methanol and acetonitrile; this points to the formation of the singlet radical pair Et2NĊHMe–ĊCl3 as a primary reaction step.
S. A. Markarian and H. Fischer, J. Chem. Soc., Chem. Commun., 1979, 1055 DOI: 10.1039/C39790001055
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