Issue 22, 1979

Redox properties of mononuclear and triply-bridged binuclear thiolato anions of oxomolybdenum(V)

Abstract

Interconversion of mononuclear [MoVO(SR)4](1; R = aryl or alkyl) and triply-bridged, binuclear [MoV2O2(SR)6Z](2; Z = OMe, OEt, or SCH2Ph) anions occurs via redox processes involving both the molybdenum and ligand thiolate centres.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 1022-1025

Redox properties of mononuclear and triply-bridged binuclear thiolato anions of oxomolybdenum(V)

J. R. Bradbury, A. G. Wedd and A. M. Bond, J. Chem. Soc., Chem. Commun., 1979, 1022 DOI: 10.1039/C39790001022

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