Cyclic 1,3-dienes react with [Mo2(CO)4(µ-C2H2)(η-C5H5)2] to give products arising from formal Diels–Alder addition to the bridging ethyne; the structure of the bicyclo[4.2.2]deca-2,4,7,9-tetraene complex [Mo2(CO)2(C10H10)(η-C5H5)2], derived from cyclo-octatetraene addition, has been determined by X-ray diffraction.
S. A. R. Knox, R. F. D. Stansfield, F. G. A. Stone, M. J. Winter and P. Woodward, J. Chem. Soc., Chem. Commun., 1979, 934 DOI: 10.1039/C39790000934
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