Spherical catalyst supports having a unimodal meso and macro pore structure were remarkably improved as supports for CO2- and CO-methanation catalysts by, respectively, high temperature calcination and coating of the macro-pore wall with very fine silica particles.
T. Inui, T. Sezume, K. Miyaji and Y. Takegami, J. Chem. Soc., Chem. Commun., 1979, 873 DOI: 10.1039/C39790000873
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