Issue 19, 1979
From the journal:

Journal of the Chemical Society, Chemical Communications

Amides of rhodium(I) and ruthenium(II), [Rh(NR2)(PPh3)2] and [RuH(NR2)(PPh3)2](R = Me3Si): novel low co-ordination number d8 and d6 metal complexes

Bekir Cetinkaya,   Michael F. Lappert  and  Sandro Torroni  

Abstract

Reaction of LiNR2(R = Me3Si) with [RhCl(PPh3)3] or [RuH(Cl)(PPh3)3] in tetrahydrofuran (thf) yields the cyclohexane-soluble, monomeric, diamagnetic amides [Rh(NR2)(PPh3)2] or [RuH(NR2)(PPh3)2], which on heating decompose with elimination of HN(SiMe3)2; the RuII compound has equivalent P atoms, but inequivalent SiMe3 environments.

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Article information

DOI
https://doi.org/10.1039/C39790000843
Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 843-844

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Amides of rhodium(I) and ruthenium(II), [Rh(NR2)(PPh3)2] and [RuH(NR2)(PPh3)2](R = Me3Si): novel low co-ordination number d8 and d6 metal complexes

B. Cetinkaya, M. F. Lappert and S. Torroni, J. Chem. Soc., Chem. Commun., 1979, 843 DOI: 10.1039/C39790000843

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