2,4-Dinitrobenzenesulphenylnitrene as a reactive intermediate
Abstract
A study of the stereospecificity of addition of the title nitrene, generated by oxidation of the corresponding sulphenamide, to cis- and trans-propenylbenzene suggests that singlet and triplet nitrene spin states are in equilibrium, with addition of the triplet state to cis-propenylbenzene being reversible.
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