Issue 19, 1979

2,4-Dinitrobenzenesulphenylnitrene as a reactive intermediate

Abstract

A study of the stereospecificity of addition of the title nitrene, generated by oxidation of the corresponding sulphenamide, to cis- and trans-propenylbenzene suggests that singlet and triplet nitrene spin states are in equilibrium, with addition of the triplet state to cis-propenylbenzene being reversible.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 833-835

2,4-Dinitrobenzenesulphenylnitrene as a reactive intermediate

R. S. Atkinson and B. D. Judkins, J. Chem. Soc., Chem. Commun., 1979, 833 DOI: 10.1039/C39790000833

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