The action of nitric acid or NO2–N2O4 mixture on [3,3-(PPh3)2-3-H-3,1,2-RhC2B9H11] affords the nitratorhodacarbaborane [3-(PPh3)-3,3-(NO3)-3,1,2-RhC2B9H11](1) whose structure has been determined by X-ray crystallography; the latter species has been shown to be a useful precursor in the synthesis of other rhodacarbadorane derivatives.
Z. Demidowicz, R. G. Teller and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1979, 831 DOI: 10.1039/C39790000831
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