The oxidative aromatic ring cleavage of 3,5-di-t-butylcatechol (1) by molecular oxygen to give the lactone (2) is catalysed by a non-enzymatic iron(II) complex co-ordinated by 2,2′-bipyridine and pyridine.
T. Funabiki, H. Sakamoto, S. Yoshida and K. Tarma, J. Chem. Soc., Chem. Commun., 1979, 754 DOI: 10.1039/C39790000754
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