The reversible oxygenation of the complexes MnLX2(L = tertiary phosphine, but not PPh3, X = action) has been investigated; these complexes resemble haemoglobin and myoglobin to a remarkable degree as reversible dioxygen carriers.
C. A. McAuliffe, H. Al-Khateeb, M. H. Jones, W. Levason, K. Minten and F. P. McCullough, J. Chem. Soc., Chem. Commun., 1979, 736 DOI: 10.1039/C39790000736
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