Issue 16, 1979

A mixed valence binuclear complex of vanadium(IV) and vanadium(V). X-Ray crystal structure of (NH4)3[V2O3(nitrotriacetate)2]·3H2O

Abstract

A deep blue mixed valence complex [VO(nta)–O–VO(nta)]3–(nta = nitrilotriacetate) was found to be in equilibrium with [VIVO(nta)(H2O)] and [VVO2(nta)]2– in aqueous solution; the crystal structure of its ammonium salt trihydrate has been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 707-708

A mixed valence binuclear complex of vanadium(IV) and vanadium(V). X-Ray crystal structure of (NH4)3[V2O3(nitrotriacetate)2]·3H2O

M. Nishizawa, K. Hirotsu, S. Ooi and K. Saito, J. Chem. Soc., Chem. Commun., 1979, 707 DOI: 10.1039/C39790000707

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