Reduction by zinc amalgam of dichloromolybdenum meso-tetra-p-tolylporphyrin [Mo(ttp)Cl2] under NO leads to two low-valent nitrosyl molybdenum porphyrin derivatives Mo(ttp)(NO)2·C6H6 and Mo(NO)(MeOH)·2C6H6; the molecular structures of both compounds were established by X-ray diffraction.
T. Diebold, M. Schappacher, B. Chevrier and R. Weiss, J. Chem. Soc., Chem. Commun., 1979, 693 DOI: 10.1039/C39790000693
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