12,16-Cyclogibborellins A9 and A12 have been isolated from the microbiological transformation of trachylobanic acid by Gibberella fujikuroi, mutant B1-41a, thus providing a notable example of the non-specificity of enzymes, catalysing the biosynthesis of fungal gibberellins; the 12,16-cyclogibberellin A9 retains gibberellin-like biological activity.
J. R. Bearder, J. MacMillan, A. Matsuo and B. O. Phinney, J. Chem. Soc., Chem. Commun., 1979, 649 DOI: 10.1039/C39790000649
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