Issue 14, 1979

Novel methadone salt containing a discrete, square-planar CuCl42– anion: X-ray crystal and molecular structure of bis(1-methyl-4-oxo-3,3-diphenylhexyldimethylammonium) tetrachlorocuprate(II)

Abstract

The crystal and molecular structure of a novel, dark green methadone salt, bis-(1-methyl-4-oxo-3,3-diphenylhexyldimethylammonium)tetrachlorocuprate-(II)(1), which has a high energy dd electronic absorption maximum at 15, 700 cm–1 in the solid state, and lacks a thermochromic transition, is reported; crystal packing forces, and not hydrogen bonding, are responsible for the discrete, square-planar geometry about copper(II) in the CuCl42– anion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 632-633

Novel methadone salt containing a discrete, square-planar CuCl42– anion: X-ray crystal and molecular structure of bis(1-methyl-4-oxo-3,3-diphenylhexyldimethylammonium) tetrachlorocuprate(II)

H. C. Nelson, S. H. Simonsen and G. W. Watt, J. Chem. Soc., Chem. Commun., 1979, 632 DOI: 10.1039/C39790000632

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements