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The first example of the stereochemistry of vinyl migration employing an optically active substrate is reported; the parallel behaviour between 1,2-migration of a vinyl group and a carbonyl group, under otherwise identical conditions, provides additional evidence for the concept of neighbouring group participation at carbonyl carbon in 1,2-acyl migrations.
R. D. Bach and D. H. Lucast, J. Chem. Soc., Chem. Commun., 1979, 593 DOI: 10.1039/C39790000593
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