The increased lability of purine nucleoside C(8)–H bonds upon co-ordination of a metal ion to the adjacent N(7) position has been used to explain the observed formation of C(8)-bonded inosine and guanosine methylmercurials, these being the first reported carbon bound species formed from the interaction of nucleosides with organomercurials.
E. Buncel, A. R. Norris, W. J. Racz and S. E. Taylor, J. Chem. Soc., Chem. Commun., 1979, 562 DOI: 10.1039/C39790000562
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