SCHEDULED MAINTENANCE
The loss of C-2 (or C-3) as methyl or methane from the butane molecular ion proceeds via concerted reactions and does not involve [methylpropane]+· as a reaction intermediate.
J. L. Holmes, P. Wolkoff and R. T. B. Rye, J. Chem. Soc., Chem. Commun., 1979, 544 DOI: 10.1039/C39790000544
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