The very fast isomerization of 2-methyl[2-13C]-pentane to 3-methyl[3-13C]pentane and the selective hydrogenolysis of methylcyclopentane to methylpentanes on iridium suggest the participation of metallocarbenes and metallocarbyne as reaction intermediates.
F. Weisang and F. G. Gault, J. Chem. Soc., Chem. Commun., 1979, 519 DOI: 10.1039/C39790000519
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