In the catalytic oxidative cyclisation of 2-(but-2-enyl)phenol (2) by (+)-[(3,2,10-η-pinene)PdOAc]2(1) in the presence of Cu(OAc)2 and O2, the η3-pinene ligand in (1) remains attached to palladium throughout the reaction, an observation which cannot be accounted for by the conventional Wacker-type catalysis.
T. Hosokawa, T. Uno and S. Murahashi, J. Chem. Soc., Chem. Commun., 1979, 475 DOI: 10.1039/C39790000475
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