Issue 9, 1979
From the journal:

Journal of the Chemical Society, Chemical Communications

Organothiometallate addition reactions with electronegative alkynes. The X-ray molecular structures of [(η5-C5H5)(CO)FeC(O)C(CF3)[double bond, length half m-dash]CHSMe], [(η5-C5H5)(CO)FeC(CF3)[double bond, length half m-dash]CHS(Me)Fe(CO)(η5-C5H5)SMe], and [(η5-C5H5)(CO)MoC(O)C(CF3)C(CF3)C(O)SMe]

Jacques E. Guerchais,   F. Le Floch-Perennou,   Francois Y. Petillon,   Alison N. Keith,   Ljubica Manojlović-Muir,   Kenneth W. Muir  and  David W. A. Sharp  

Abstract

Addition of F3CC[triple bond, length half m-dash]CH and F3CC[triple bond, length half m-dash]CCF3 to [(η5-C5H5)FeSMe(CO)2] gives mono- and bi-nuclear methylthio-alkenyl complexes, and with [(η5-C5H5)Mo(CO)3]2 and MeSSMe a novel six-membered metallocycle incorporating S-methyl thioester and η3-acryloyl functions is obtained.

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Article information

DOI
https://doi.org/10.1039/C39790000410
Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 410-411

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Organothiometallate addition reactions with electronegative alkynes. The X-ray molecular structures of [(η5-C5H5)(CO)FeC(O)C(CF3)[double bond, length half m-dash]CHSMe], [(η5-C5H5)(CO)FeC(CF3)[double bond, length half m-dash]CHS(Me)Fe(CO)(η5-C5H5)SMe], and [(η5-C5H5)(CO)MoC(O)C(CF3)C(CF3)C(O)SMe]

J. E. Guerchais, F. Le Floch-Perennou, F. Y. Petillon, A. N. Keith, L. Manojlović-Muir, K. W. Muir and D. W. A. Sharp, J. Chem. Soc., Chem. Commun., 1979, 410 DOI: 10.1039/C39790000410

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