The microwave spectrum of S2Cl2 has been observed and analysed, leading to precise geometrical parameters and 35Cl quadrupole coupling constants; the SS bond length is shorter than the standard single bond length but not as short as that in S2F2.
C. J. Marsden, R. D. Brown and P. D. Godfrey, J. Chem. Soc., Chem. Commun., 1979, 399 DOI: 10.1039/C39790000399
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