The ground state of thioformaldehyde radical anion (2B1) is calculated to be bound, near to its quasiplanar equilibrium geometry; the acquisition of an electron: H2C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
S + e–→ H2CS·– should cause only small changes in the H2C group but a lengthening of the CS bond.
P. Rosmus and H. Bock, J. Chem. Soc., Chem. Commun., 1979, 334 DOI: 10.1039/C39790000334
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