The dinuclear hydrido-complex [(η6-C6Me6)Ru(µ-H)2(µ-Cl)Ru(η6-C6Me6)]Cl reacts with mono-olefins to give the corresponding alkanes and either η3-allylruthenium(II) or dieneruthenium(0) complexes; it also catalyses efficient homogeneous hydrogenation of a range of arenes to the corresponding cyclohexanes under mild conditions.
M. A. Bennett, T. Huang and T. W. Turney, J. Chem. Soc., Chem. Commun., 1979, 312 DOI: 10.1039/C39790000312
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