The (η3-acryloyl)tricarbonylferrate (1) reacted with the acyl halides (2) affording the unexpected 1:1 adducts, which were deduced to be the novel halogenodicarbonyl(η-2-acyloxy)ferracyclopent-2-en-5-onates (3) derived by the carbonylation of an η3-vinylcarbene ligand.
T. Mitsudo, H. Watanabe, Y. Watanabe and Y. Takegami, J. Chem. Soc., Chem. Commun., 1979, 265 DOI: 10.1039/C39790000265
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