Issue 6, 1979

Kinetics and stereochemistry of elimination reactions in tertiary nitroalkanes: a measure of the nucleofugacity of nitrite ion from a saturated carbon

Abstract

The reaction of methoxide ion in 50%, (v/v) methanol–dimethyl sulphoxide with p-(2-methyl-2-nitro-propyl)nitrobenzene and its derivatives shows that the elimination reaction taking place is a concerted anti-periplanar E2 process and that the nucleofugacity of nitrite ion in this system lies between that of bromide and chloride ions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 259-260

Kinetics and stereochemistry of elimination reactions in tertiary nitroalkanes: a measure of the nucleofugacity of nitrite ion from a saturated carbon

P. G. Gray, R. K. Norris and T. A. Wright, J. Chem. Soc., Chem. Commun., 1979, 259 DOI: 10.1039/C39790000259

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