Issue 5, 1979

The electron spin resonance spectra of cyclopropylacyl radicals: spectroscopically distinguishable σ-radicals related by rotation about a single bond

Abstract

Below –90°C, cyclopropylacyl radicals show two e.s.r. spectra which are associated with the two conformers, of approximately equal stability, in which the plane containing the acyl group bisects the cyclopropyl ring, with a two-fold rotational barrier of about 17·5 kJ mol–1.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 217-218

The electron spin resonance spectra of cyclopropylacyl radicals: spectroscopically distinguishable σ-radicals related by rotation about a single bond

P. M. Blum, A. G. Davies and R. Sutcliffe, J. Chem. Soc., Chem. Commun., 1979, 217 DOI: 10.1039/C39790000217

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