The reaction of allylic bromides with bromoform and aqueous base under phase transfer conditions is strongly dependent on the catalyst; when benzyltriethylammonium chloride is used, the major primary product is a 4,4,4-tribromobut-1-ene.
M. S. Baird, A. G. W. Baxter, B. R. J. Devlin and R. J. G. Searle, J. Chem. Soc., Chem. Commun., 1979, 210 DOI: 10.1039/C39790000210
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