Issue 4, 1979

Magnetic properties of hemichrome salts [derivatives of iron(III) octaethylporphyrin complexes]: the presence of a ‘spin-equilibrium’

Abstract

The temperature dependence of the effective magnetic moments of hemichrome salts, namely bis-(pyridine)octaethylporphinato iron(III) perchloroate and hexafluorophosphate, in both the solid state and in solution are interpreted in terms of a spin-equilibrium between two states, predominantly S′=½ and S′= 5/2.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 151-152

Magnetic properties of hemichrome salts [derivatives of iron(III) octaethylporphyrin complexes]: the presence of a ‘spin-equilibrium’

H. A. O. Hill, P. D. Skyte, J. W. Buchler, H. Lueken, M. Tonn, A. K. Gregson and G. Pellizer, J. Chem. Soc., Chem. Commun., 1979, 151 DOI: 10.1039/C39790000151

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