Issue 3, 1979

Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C5H5)2]2[Sb4Cl12O]}2·2C6H6

Abstract

The product of the reaction between SbCl3 and Fe(η-C5H5)2 in benzene is shown by X-ray crystallography to possess an octameric unit [Sb4Cl12O]24–, with terminal and bridging chloride groups and bridging oxo-groups; the ferricenium cations are shown to adopt the eclipsed configurations.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 143-144

Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C5H5)2]2[Sb4Cl12O]}2·2C6H6

A. L. Rheingold, A. G. Landers, P. Dahlstrom and J. Zubieta, J. Chem. Soc., Chem. Commun., 1979, 143 DOI: 10.1039/C39790000143

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