Issue 1, 1979

Isomers of B20H26: elucidation of the structure of 6,6′-Bi(nido-decaboranyl) by 11B-{1H} and 1H-{11B} n.m.r. spectroscopy

Abstract

The structure of one of the B20H26 isomers formed by thermolysis of nido-decaborane in the presence of tetrahydrothiophen has been shown to be 6,6′-bi(nido-decaboranyl) by means of 1H-{11B} n.m.r. spectroscopy in conjuction with ‘partially relaxed’11B and 11B-{1H} n.m.r. spectroscopy; it is the largest neutral borane yet characterised.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 16-17

Isomers of B20H26: elucidation of the structure of 6,6′-Bi(nido-decaboranyl) by 11B-{1H} and 1H-{11B} n.m.r. spectroscopy

S. K. Boocock, N. N. Greenwood, J. D. Kennedy and D. Taylorson, J. Chem. Soc., Chem. Commun., 1979, 16 DOI: 10.1039/C39790000016

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