The gas-phase pyrolysis of dithioacetates is a concerted unimolecular process. The measured rates of these reactions agree well with rates calculated simply from the corresponding thiol- and thion-acetates.
N. Al-Awadi, D. B. Bigley and R. E. Gabbott, J. Chem. Soc., Perkin Trans. 2, 1978, 1223 DOI: 10.1039/P29780001223
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