E.s.r. measurements indicate that aromatic nitroso-compounds add to olefins by one-electron transfer from C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
C to NO bonds to give nitroxide radicals. The spectra of such radicals formed from 2,4,6-trichloronitrosobenzene and olefins having a wide range of substituent groups are tabulated. Possible reactions subsequent to the initial addition are proposed.
D. Mulvey and W. A. Waters, J. Chem. Soc., Perkin Trans. 2, 1978, 1059 DOI: 10.1039/P29780001059
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