Further data are presented to illustrate the relationship of the S1→S0 non-radiative rate constant and the triplet energy of homologous series with Taft polar substituent constants. The magnitude of the inductive effect exerted by a given substituent depends on the site of substitution and the number of π electrons in the chromophore.
L. A. King, J. Chem. Soc., Perkin Trans. 2, 1978, 472 DOI: 10.1039/P29780000472
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