Variable temperature 1H and 13C n.m.r. spectra of N-benzyl-NO-dimethyl- and NO-dimethyl-N-(1-arylethyl)hydroxylamines in deuteriotoluene are reported. The results are interpreted in terms of N-inversion rather than N–O rotation as the rate-limiting process governing the observation of non-equivalence.
T. B. Posner, D. A. Couch and C. D. Hall, J. Chem. Soc., Perkin Trans. 2, 1978, 450 DOI: 10.1039/P29780000450
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