Issue 10, 1978

Reaction of benzoyl(phenyl)acetaldehyde with N-phenylhydroxylamine: a re-examination

Abstract

N-(2-Benzoylstyryl)-N-phenylhydroxylamine (3), the primary condensation product between benzoyl(phenyl)-acetaldehyde (1) and N-phenylhydroxylamine (2) has been isolated, and its tautomerism studied. This compound readily dehydrates to C-benzoyl-CN-diphenylketen imine (5) which, in turn, gives the final products by addition, respectively, of water [benzoyl(phenyl)acetanilide (12)], acetic acid [acetylated benzoyl(phenyl)acetanilide (7)], N-phenylhydroxylamine [2-phenylimino-3,4,5-triphenyloxazoline (10)], or benzoylphenylacetaldehyde [2-benzoylstyryl [N-phenyl(benzoyl)phenylacetimidate or tautomer (9), produced].

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1978, 1113-1116

Reaction of benzoyl(phenyl)acetaldehyde with N-phenylhydroxylamine: a re-examination

F. De Sarlo and G. Renzi, J. Chem. Soc., Perkin Trans. 1, 1978, 1113 DOI: 10.1039/P19780001113

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements