The formation of cis-and trans-epoxy-alcohols by treatment of steroidal epoxy-ketones with sodium borohydride is analysed in terms of the direction of attack on the corresponding unsubstituted ketones, and the steric hindrance exerted by the epoxide ring.
M. Weissenberg and E. Glotter, J. Chem. Soc., Perkin Trans. 1, 1978, 568 DOI: 10.1039/P19780000568
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