Issue 4, 1978

Heterocyclic polyfluoro-compounds. Part 25. The photochemical addition of ethylene to pentafluoropyridine: formation of 1 : 1- and 2 : 1-adducts

Abstract

Ethylene adds photochemically to pentafluoropyridine to yield 1,2,4,5,6-pentafluoro-3-azabicyclo[4.2.0]octa-2,4-diene (1) and 1,2,5,6,8-pentafluoro-7-azatricyclo[4.2.2.02.5]dec-7-ene (2). The adduct (2) is also slowly formed thermally from (1). Water converts the CF:N group in adduct (2) into CO·NH, and ethanol converts it into C(OEt):N. Lithium aluminium hydride effects complete reduction and replacement of fluorine atoms by hydrogen.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1978, 363-365

Heterocyclic polyfluoro-compounds. Part 25. The photochemical addition of ethylene to pentafluoropyridine: formation of 1 : 1- and 2 : 1-adducts

M. G. Barlow, D. E. Brown and R. N. Haszeldine, J. Chem. Soc., Perkin Trans. 1, 1978, 363 DOI: 10.1039/P19780000363

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements