Issue 0, 1978
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Ligand–ligand interactions and low frquency vibrations in Ir(C2H4)4Cl and [Ir(C2H4)2Cl]2 studied by inelastic neutron scattering and optical spectroscopy

Joseph Howard  and  Thomas C. Waddington  

Abstract

Incoherent inelastic neutron scattering spectra of Ir(C2H4)4Cl and [Ir(C2H4)2Cl]2 have been obtained and a model is porposed for the interaction between the ethylene ligands in Ir(C2H4)4Cl. For this complex the torison of the axial C2H4 ligand is assigned at 45 ± 4 cm–1 and the in-phase and out-of-phase torsions of the equatorial ligands assigned at 172 ± 10 and 240 ± 10 cm–1, respectively.

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Article information

DOI
https://doi.org/10.1039/F29787401275
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1978,74, 1275-1284

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Ligand–ligand interactions and low frquency vibrations in Ir(C2H4)4Cl and [Ir(C2H4)2Cl]2 studied by inelastic neutron scattering and optical spectroscopy

J. Howard and T. C. Waddington, J. Chem. Soc., Faraday Trans. 2, 1978, 74, 1275 DOI: 10.1039/F29787401275

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