The rates of release of ligand L from [FeII(CN)5L]n– complexes {L = unidentate terminal diamines NH2-[CH2]n NH2(n= 3–6) unprotonated or monoprotonated} have been measured in aqueous solutions at various pH and temperatures. The kinetic parameters are interpreted on the basis of solvation effects.
N. E. Katz, M. A. Blesa, J. A. Olabe and P. J. Aymonino, J. Chem. Soc., Dalton Trans., 1978, 1603 DOI: 10.1039/DT9780001603
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