Platinum(II) complexes with 2,2′-bipyrimidine, [PtX2(bipym)](X = CN, Cl, or SCN; X2= C2O4), [Pt(bipym)2]-[PtX4](X = Cl or CN), and [Pt2(NH3)4(bipym)][NO3]4, have been synthesised and characterised. Intense absorption bands in the visible region assigned to metal–metal interactions are related to strong hydrogen bonding involving the unco-ordinated heterocyclic nitrogen atoms.
P. M. Kiernan and A. Ludi, J. Chem. Soc., Dalton Trans., 1978, 1127 DOI: 10.1039/DT9780001127
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